Effect of protic agents on the catalytic activity of supported palladium catalysts in the copolymerization of ethylene with carbon monoxide

Autor:	K. A. Alferov, G. P. Belov, O. M. Chukanova
Rok vydání:	2011
Předmět:	chemistry.chemical_compound Ethylene chemistry Formic acid Copolymer chemistry.chemical_element General Chemistry Methanol Photochemistry Toluene Palladium Catalysis Carbon monoxide
Zdroj:	Russian Chemical Bulletin. 60:1858-1861
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-011-0280-y
Popis:	The influence of the addition of different amounts of MeOH, H2O, and HCOOH on the activity of supported palladium catalyst in the copolymerization of CO with ethylene and the kinetic regularities of this reaction were studied for the first time. The maximum yield of the copolymer is attained when MeOH and H2O or HCOOH and H2O are simultaneously introduced into the reaction medium (toluene). The results obtained are consistent with the concepts about the role of protic agents in the formation of active intermediates and polymer molecules in the copolymerization of CO with ethylene in the presence of the homogeneous catalytic systems.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::63b2286e5fe5c47928dfefaad4f4f2fd https://doi.org/10.1007/s11172-011-0280-y Zobrazit plný text záznamu Full text from SpringerLink