X-ray structure and vibrational spectroscopy of a cobalt(II) complex prepared with excess of 4-hydroxybenzhydrazide

Autor:	Halina Zasłona, Piotr Drożdżewski
Rok vydání:	2011
Předmět:	chemistry.chemical_classification X-ray chemistry.chemical_element Infrared spectroscopy 4-hydroxybenzhydrazide Polymer symbols.namesake Crystallography chemistry Lattice (order) Materials Chemistry symbols Molecule Physical and Theoretical Chemistry Raman spectroscopy Cobalt
Zdroj:	Journal of Coordination Chemistry. 64:2262-2273
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958972.2011.594885
Popis:	A new cobalt(II) complex was obtained from CH3OH/H2O solution containing CoSO4 and 4-hydroxybenzhydrazide (4hbah) in 1 : 3 molar ratio. The crystals are composed of polymer chains [Co(4hbah)2(μ-SO4)] n accompanied by lattice H2O and CH3OH forming the 3-D network. The CH3OH molecules are highly disordered. For the assignment of IR and Raman spectra, the O,N-deuterated compound was prepared and DFT calculations were carried out.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::639af49b1b552684a8960e12a4322b92 https://doi.org/10.1080/00958972.2011.594885 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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