Hyperbranched polyester poly[3-(morpholin-4-yl)propionates] and their copper(II) complexes
| Autor: | A. S. Basalaev, N. A. Ulakhovich, E. M. Khasanova, Marianna P. Kutyreva, S. V. Yurtaeva, G. A. Kutyrev, A. R. Gataulina |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
Denticity 010405 organic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Copper Electron spectroscopy 0104 chemical sciences Polyester chemistry.chemical_compound chemistry Morpholine Polymer chemistry Propionate Surface modification Propionates |
| Zdroj: | Russian Journal of General Chemistry. 87:1995-2005 |
| ISSN: | 1608-3350 1070-3632 |
| Popis: | Novel polydentate ligands on the basis of second- and third-generation hyperbranched polyesters containing terminal poly[3-(morpholin-4-yl)propionate] groups and their 6 : 1 and 13 : 1 polynuclear copper(II) complexes were synthesized. The degree of functionalization of the polyesters with morpholine increases in going from the second (56%) to third generation (68%). According to IR and electronic spectroscopy data, each coordination entity in the complexes is an isolated paramagnetic center of the formula CuN2O2Solv2 (Solv = H2O, DMSO). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|