Ci Symmetric and Non-Centrosymmetric Crystalline Complexes of [60]Fullerene with Octakis(dimethylamino)porphyrazinato-Copper(II) and -Nickel(II)

Autor:	Detlev H. Hochmuth, David J. Williams, Anthony G. M. Barrett, Andrew J. P. White, Sarah L. J. Michel, Brian M. Hoffman
Rok vydání:	2000
Předmět:	Inorganic Chemistry chemistry.chemical_compound Nickel Crystallography Fullerene chemistry Supramolecular chemistry chemistry.chemical_element Porphyrazine Photochemistry Copper
Zdroj:	European Journal of Inorganic Chemistry. 2000:593-596
ISSN:	1099-0682 1434-1948
DOI:	10.1002/(sici)1099-0682(200004)2000:4<593::aid-ejic593>3.0.co;2-n
Popis:	X-ray structural analysis of octakis(dimethylamino)porphyrazinato-metallo(II)·[60]fullerene complexes (M = Cu2+ and Ni2+) surprisingly revealed two totally different supramolecular structures, the first exhibiting a Ci symmetric sandwich complex of two slightly dished porphyrazine units enclosing one fullerene sphere, the other featuring a noncentrosymmetric 1:1 complex with a strongly warped porphyrazine unit.
Databáze:	OpenAIRE
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