One-step and selective approach to silicon-containing exo-norbornenes

Autor:	E. V. Bermesheva, M. A. Guseva, M. V. Bermeshev, P. P. Chapala
Rok vydání:	2019
Předmět:	chemistry.chemical_compound Multidisciplinary Silanes chemistry Silicon Hydrosilylation chemistry.chemical_element One-Step Alkylation Isomerization Combinatorial chemistry Group 2 organometallic chemistry Norbornene
Zdroj:	Доклады Академии наук. 486:189-192
ISSN:	0869-5652
DOI:	10.31857/s0869-56524862189-192
Popis:	One-step and selective approach to the synthesis of Si-containing exo-norbornenes has been developed based on hydrosilylation reaction of norbornadiene-2,5 with unactivated silanes using Pd-complexes in the presence of bulky ligands. This approach leads to only exo-isomers of norbornene derivatives. The absence of alkylation step by organometallic compounds or photochemical isomerization makes the suggested approach promising for the synthesis of new polymeric materials with desired properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6355f47d11f6a0fa64e87cf49b657895 https://doi.org/10.31857/s0869-56524862189-192 Zobrazit plný text záznamu