Tungsten(II) Alkylimido Complexes from Insertion of Nitriles into Tungsten Hydride: Alkylideneamido Intermediate Stage and Nitrene Group Transfer to Isocyanide

Autor:	Hidetake Seino, Yasushi Mizobe, Qi Xiu Dai
Rok vydání:	2012
Předmět:	Hydride Nitrene Isocyanide Organic Chemistry chemistry.chemical_element Tungsten Photochemistry Toluene Intermediate stage Inorganic Chemistry chemistry.chemical_compound chemistry Group (periodic table) Polymer chemistry Physical and Theoretical Chemistry
Zdroj:	Organometallics. 31:4933-4936
ISSN:	1520-6041 0276-7333
Popis:	The tetrahydrido complex [WH4(κ4-P4)] (P4 = meso-o-C6H4(PPhCH2CH2PPh2)2) reacted with aliphatic nitriles AkCN at 80 °C in toluene to afford a series of the imido complexes, [W(NCH2Ak)(κ4-P4)] (2). ...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6353004b47d78806a218d89897c5d057 https://doi.org/10.1021/om3004338 Zobrazit plný text záznamu