Hydrogen separation and purification using polysulfone acrylate–zeolite mixed matrix membranes
Autor: | Asim Laeeq Khan, Cristina Minguillón, Angels Cano-Odena, Biotza Gutiérrez, Ivo F.J. Vankelecom |
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Rok vydání: | 2010 |
Předmět: |
chemistry.chemical_classification
Acrylate Materials science Filtration and Separation Polymer Biochemistry Hydrogen purifier chemistry.chemical_compound Membrane chemistry Chemical engineering Organic chemistry General Materials Science Polysulfone Gas separation Physical and Theoretical Chemistry Selectivity Zeolite |
Zdroj: | Journal of Membrane Science. 350:340-346 |
ISSN: | 0376-7388 |
DOI: | 10.1016/j.memsci.2010.01.009 |
Popis: | Mixed matrix membranes were prepared from derivatized polysulfone and zeolite particles. Aminopropyltrimethoxysilane was used as coupling agent to covalently link zeolite particles with the acrylate modified polymer. The mixed gas selectivity for H2/CO2 separation increased from 1.53 for pure polysulfone to 3.57 at 40% zeolite loading. The results suggest that the covalent linkage of polymer and filler results in defect free membranes. The effect of different operating conditions (feed pressure, temperature and CO2 feed concentration) was also studied. |
Databáze: | OpenAIRE |
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