Structural, spectral, optical and Z-Scan budding studies of (E)-N′-(4-bromobenzylidene)-4-fluorobenzohydrazide
| Autor: | N. Latha, Barathi Diravidamani, D. Ramarajan, S. Sudha |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
Infrared Hyperpolarizability Atomic and Molecular Physics and Optics Spectral line Electronic Optical and Magnetic Materials symbols.namesake Fourier transform symbols Molecule Physical chemistry Density functional theory Z-scan technique Electrical and Electronic Engineering Fourier transform infrared spectroscopy |
| Zdroj: | Optik. 247:167869 |
| ISSN: | 0030-4026 |
| DOI: | 10.1016/j.ijleo.2021.167869 |
| Popis: | A Schiff base third-order nonlinear optical material (E)-N′-(4-bromobenzylidene)− 4-fluorobenzohydrazide (BBFBH) was synthesized. It was characterized by victimization chemical analysis techniques like Fourier Transform Infrared (FTIR), Nuclear Magnetic Resonance (NMR), Ultra-Violet (UV) spectra and Z-scan. The molecular structure of hydrazide derivative C14H10BrFN2O has been studied with Gaussian 09 using density functional theory. The experimental and theoretical FTIR spectral peaks were analyzed and compared. The absorption in the Ultra-Violet region makes the material to be suitable for optical activity. The static first-order hyperpolarizability (β0) were calculated and compared with carbamide. The molecule's potential and compatibility in optical limiting applications are revealed by Z-scan investigations. |
| Databáze: | OpenAIRE |
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