Expeditious and efficient syntheses of pure 4-methyl and 4,6-disubstituted dibenzothiophenes

Autor:	Paul Caubere, Sandrine Adach-Becker, Catherine Kuehm-Caubère, Yves Fort
Rok vydání:	1996
Předmět:	chemistry.chemical_compound Scale (ratio) chemistry Dibenzothiophene Organic Chemistry Drug Discovery Organic chemistry Biochemistry
Zdroj:	Tetrahedron. 52:9087-9092
ISSN:	0040-4020
DOI:	10.1016/0040-4020(96)00459-0
Popis:	4-Lithio and 4,6-dilithiodibenzothiophenes were efficiently obtained by lithiation of dibenzothiophene with BuLi and BuLi-TMEDA, respectively. Very pure 4-methyl- and 4,6-dimethyldibenzothiophenes, substrates of great request in hydrosulfurization studies were easily prepared, on large scale and in excellent yields.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::633b8a3f8373503e511ae3ec86e43755 https://doi.org/10.1016/0040-4020(96)00459-0 Zobrazit plný text záznamu Full Text from ScienceDirect