Electron rich acetylide clusters; molecular and electronic structure and reactions of Os3(CO)7(µ2-η2-CCR)2(µ-PPh2)2(R = Ph, Pri); 50-electron species with expanded metal frameworks
| Autor: | Nicholas J. Taylor, Andrew A. Cherkas, Arthur J. Carty |
|---|---|
| Rok vydání: | 1990 |
| Předmět: | |
| Zdroj: | J. Chem. Soc., Chem. Commun.. :385-387 |
| ISSN: | 0022-4936 |
| DOI: | 10.1039/c39900000385 |
| Popis: | The reactivity of the 50-electron acetylide clusters Os3(CO)7(µ2-η2-CCR)2(µ-PPh2)2[(1a) R = Ph; (1b) R = Pri] which have unusual expanded Os3 frameworks, is dominated by nucleophilic addition at the metals: the molecular structures of Os3(CO)7(µ2-η2-CCPri)2(µ-PPh2)2 and the ethylamine adduct of (1a), Os3(CO)6(µ2-η2-CCPh)(η1-CCPh)(µ-PPh2)2(EtNH2)2(2a) have been determined by X-ray diffraction and their electronic structures probed by EHMO calculations. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|