Copper(I) complexes of N-thioacylamido(thio)phosphates and triphenylphosphine

Autor:	Igor A. Litvinov, Alexander Yu. Verat, Nail G. Zabirov, Felix D. Sokolov, Dmitry B. Krivolapov, Vasiliy V. Brusko, Maria G. Babashkina
Rok vydání:	2006
Předmět:	Stereochemistry Thio chemistry.chemical_element Crystal structure Medicinal chemistry Copper Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Molecule Chelation Physical and Theoretical Chemistry Triphenylphosphine
Zdroj:	Inorganica Chimica Acta. 359:475-483
ISSN:	0020-1693
DOI:	10.1016/j.ica.2005.09.061
Popis:	Heteroligand copper(I) complexes of bi- or bis-bidentate acylamidophosphates PhC(S)NHP(S)(OPr-i)2, PhC(S)NHP(O)(OPr-i)2, Et2NC(S)NHP(S)(OPr-i)2, PhNHC(S)NHP(S)(OPr-i)2, N-(4-aminobenzo-15-crown-5)-C(S)NHP(S)(OPr-i)2, N,N-(1,10-diaza-18-crown-6)-[C(S)NHP(S)(OPr-i)2]2, and triphenylphosphine were prepared and characterised. Copper is bound by two PPh3 and one SCNPX (X = O, S) fragment of chelating ligand in all cases. Triphenylphosphine molecules reversibly dissociate in solution. Details of the X-ray structures of (Ph3P)2Cu[PhC(S)NP(S)(OPr-i)2] and (Ph3P)2Cu[Et2NC(S)NP(S)(OPr-i)2] are reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::63136722eda86f5d4b484a7afb88222c https://doi.org/10.1016/j.ica.2005.09.061 Zobrazit plný text záznamu Full Text from ScienceDirect