Free-radical polymerizations of and in deep eutectic solvents: Green synthesis of functional materials
| Autor: | Josué D. Mota-Morales, R. J. Sánchez-Leija, Gabriel Luna-Bárcenas, Arturo Carranza, Francisco del Monte, John A. Pojman |
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| Rok vydání: | 2018 |
| Předmět: |
Green chemistry
chemistry.chemical_classification Materials science Polymers and Plastics Organic Chemistry Radical polymerization 02 engineering and technology Surfaces and Interfaces Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Chemical reaction 0104 chemical sciences Deep eutectic solvent chemistry.chemical_compound Monomer chemistry Polymerization Ionic liquid Materials Chemistry Ceramics and Composites Organic chemistry 0210 nano-technology |
| Zdroj: | Progress in Polymer Science. 78:139-153 |
| ISSN: | 0079-6700 |
| DOI: | 10.1016/j.progpolymsci.2017.09.005 |
| Popis: | The increasing environmental awareness has led to the search for alternative reaction media to reduce or eliminate the use of organic solvents in polymer science. Deep eutectic solvents (DESs), a subclass of ionic liquids, have emerged as sustainable solvents for a plethora of chemical reactions. In this Trend Article, DES utilization in free-radical polymerizations will be discussed. Two main fields of application are reported. In the first section, monomers able to undergo free-radical polymerization while taking part in a DES, as hydrogen bond donor or ammonium salt, so called DES monomers, are presented. In the second section, the role of DESs as solvents, where the polymerization takes place, either in the same phase or in an emulsion, is described. Finally, the properties of the polymers resulting from these particular methods of synthesis are discussed with emphasis on their green aspects. |
| Databáze: | OpenAIRE |
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