Synthesis and curing of a novel amino-containing phthalonitrile derivative

Autor:	Ke Zeng, Hong Fei Zhou, Hai Bing Zhou, Wen Rui Tang, Yan Tang, Yipeng Wang, Tao Liu, Gang Yang, Ke Zhou
Rok vydání:	2007
Předmět:	chemistry.chemical_classification Phthalonitrile chemistry.chemical_compound Aniline chemistry Nucleophile Hydrochloride Polymer chemistry Proton NMR General Chemistry Polymer Thermal analysis Curing (chemistry)
Zdroj:	Chinese Chemical Letters. 18:523-526
ISSN:	1001-8417
DOI:	10.1016/j.cclet.2007.03.035
Popis:	A novel phthalonitrile derivative containing an amino group, 3,5-bis(3,4-dicyanophenoxy)aniline (CPA), was synthesized via a nucleophilic displacement of 4-nitrophthalonitrile and 5-aminoresorcinol hydrochloride. The structure of CPA was confirmed by Fourier transform infrared spectra (FT-IR) and nuclear magnetic resonance (1H NMR). Thermal analysis performed on CPA revealed that the novel phthalonitrile derivative showed a self-promotion curing behavior and the resulting polymer exhibited outstanding heat-resistance.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::62fc2c062984ff83f7eede82b63d2605 https://doi.org/10.1016/j.cclet.2007.03.035 Zobrazit plný text záznamu Full Text from ScienceDirect