Synthesis of Nanocrystalline Ce0.8Gd0.2O2−δ Electrolyte Materials for IT-SOFC
| Autor: | Saradha T, Kyeongsoon Park, H K Hwang, J W Choi |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
Materials science
Biomedical Engineering Analytical chemistry Sintering Bioengineering General Chemistry Electrolyte Crystal structure Conductivity Condensed Matter Physics Fluorite Nanocrystalline material law.invention law Electrical resistivity and conductivity General Materials Science Calcination |
| Zdroj: | Journal of Nanoscience and Nanotechnology. 10:7703-7706 |
| ISSN: | 1533-4880 |
| DOI: | 10.1166/jnn.2010.2790 |
| Popis: | We successfully synthesized nano-sized Ce(0.8)Gd(0.2)O(2-delta) powders by combustion method, using gelatin as fuel. The calcined powders showed high-quality characteristics, i.e., nano-scale size (14-35 nm) and narrow size distribution. The structural, morphological, and electrical characteristics of the sintered Ce(0.8)Gd(0.2)O(2-delta) were studied systematically, depending on sintering temperature. The crystal structure of the Ce(0.8)Gd(0.2)O(2-delta) belonged to the cubic fluorite structure. The gelatin-assisted combustion synthesized Ce(0.8)Gd(0.2)O(2-delta) powders allowed to sinter well at low temperature for dense and ultra-fine Ce(0.8)Gd(0.2)O(2-delta) electrolyte with good electrical conductivity. The sintering temperature of the Ce(0.8)Gd(0.2)O2 powder was approximately 300 degrees C lower than that of conventional solid-state synthesized powder. The nanopowder produced was sintered into pellets with relative densities over 99.1% of the theoretical value even at 1400 degrees C. The Ce(0.8)Gd(0.2)O(2-delta) sintered at 1400 degrees C exhibited a conductivity of 0.101 S/cm at 800 degrees C in air. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|