Synthesis, Characterization and Copolymerization of 2-[4-(2-Oxazolinyl)-Phenoxyjethyl Methacrylate with Hema and Copolymer Crosslinking Reactions

Autor:	Yongpeng Xue, Bill M. Culbertson, Yuhua Tong
Rok vydání:	1998
Předmět:	Materials science Polymers and Plastics Radical polymerization Cationic polymerization General Chemistry Oxazoline Methacrylate chemistry.chemical_compound Monomer chemistry Polymerization Polymer chemistry Materials Chemistry Ceramics and Composites Copolymer Organic chemistry Bifunctional
Zdroj:	Journal of Macromolecular Science, Part A. 35:1651-1666
ISSN:	1520-5738 1060-1325
DOI:	10.1080/10601329808000977
Popis:	The bifunctional monomer 2-[4-(2-oxazolinyl) phenoxy]ethyl meth-acrylate [OPEM] was prepared in good yield using the starting material 4-cyanophenol, via a multi-step synthesis method. Since OPEM is very similar to 2-hydroxyethyl methacrylate [HEMA], OPEM readily copolymerizes with HEMA, using typical free radical initiators. In the presence of proton sources, such as alcohols and acids and using cationic initiators, the oxazoline groups undergo ring-opening polymerization, resulting in crosslinking. The free radical copolymerization and cationic polymerization were investigated by differential scanning calorimetry [DSC]. † Currently at Rutgers University, New Brunswick, NJ 08903
Databáze:	OpenAIRE
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