Photopromoted methoxycarbonylation of olefin with methyl formate by Co(OAc)2

Autor:	Ying Na Cui, Guang Yun Zhou, Ying Ping Jia, Jing Mei Yin, Shen Min Li, Da Bin Gao
Rok vydání:	2007
Předmět:	Olefin fiber chemistry.chemical_compound Cobalt acetate chemistry Methyl formate Organic chemistry General Chemistry Medicinal chemistry Catalysis
Zdroj:	Chinese Chemical Letters. 18:17-20
ISSN:	1001-8417
DOI:	10.1016/j.cclet.2006.11.021
Popis:	The photopromoted methoxycarbonylation of olefin with methyl formate catalyzed by Co(OAc)2 at ambient conditions has been carried out. The results indicated that the reaction activity increased with the increasing temperature. Methyl formate decomposed into CO and CH3OH firstly under irradiation, and then the methoxycarbonylation of olefin proceeded under catalysis of Co(OAc)2. The mechanism of methyl formate participating in the methoxycarbonylation is verified by the IR analysis and the labeling experiments of CD3OD and CH318OH.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::625c1ad506295b0bf636371072012b8d https://doi.org/10.1016/j.cclet.2006.11.021 Zobrazit plný text záznamu Full Text from ScienceDirect