ChemInform Abstract: Synthesis of R2R′2C4B8H8 Tetracarbon Carboranes from (η6-Cyclooctatriene)iron(dicarbahexaborane) Complexes via Mixed-Ligand Thermal Fusion

Autor:	Russell N. Grimes, Kathleen K. Fonda
Rok vydání:	1990
Předmět:	Solvent Change over time Fusion Crystallography Work (thermodynamics) Chemistry Thermal General Medicine Mixed ligand Carbon-13 NMR
Zdroj:	ChemInform. 21
ISSN:	0931-7597
DOI:	10.1002/chin.199028213
Popis:	Reactions of (R2C2B4H4)Fe(η6-C8H10) complexes with Na+R′2C2B4H−5 salts (R = C2H5, n-C4H9, CH2C6H5; R′ = CH3, C2H5, n-C4H9, CH2C6H5) at 150°C in the absence of solvent gave products of the general formula R2R′2C4B8H8, accompanied in each case by R4C4B8H8 carboranes. 11B, 1H, and 13C NMR Studies of the R2R′2C4B8H8 clusters indicated that each consists of two isomers consistent with the “open” and “closed” geometries identified in earlier work on R4C4B8H8 clusters, and that the isomer ratios do not change over time in solution at room temperature.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::623445c12a5677174c7a281480584266 https://doi.org/10.1002/chin.199028213 Zobrazit plný text záznamu Plný text