Spirophosphazenes and the parent triazaphosphole : differences and similarity in chemical reactivity

Autor:	O. S. Diallo, Jean Barrans, L. Lopez
Rok vydání:	1991
Předmět:	Organic Chemistry chemistry.chemical_element Protonation Nuclear magnetic resonance spectroscopy Biochemistry Nitrogen Catalysis Hydrolysis chemistry Similarity (network science) Nitrogen atom Computational chemistry Drug Discovery 31p nmr spectroscopy
Zdroj:	Tetrahedron Letters. 32:501-504
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)79479-2
Popis:	The first step of hydrolysis of compounds 1 , 2 and 4 involves the protonation of the PN nitrogen atom. 3 does not react with water in the absence of a catalyst. Protonation of compounds 1 – 3 by a strong acid such as CF3SO3H is studied by 15N and 31P nmr spectroscopy. In all cases the PN nitrogen appears to be the strongest basic site.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6219c4406a20bf4f553aee8555bd2843 https://doi.org/10.1016/s0040-4039(00)79479-2 Zobrazit plný text záznamu