Efficient Chemoselective Oxidation of Phenylmethanols to Aldehydes with Iodosobenzene

Autor:	Konstantinos Mertis, Nikos Psaroudakis, Pericles Stavropoulos, Patrina Paraskevopoulou, Eleftheria Petalidou
Rok vydání:	2005
Předmět:	Solvent Iodosobenzene chemistry.chemical_compound chemistry Reagent chemistry.chemical_element Organic chemistry Phenylmethanol General Chemistry Chemoselectivity Iodine
Zdroj:	Monatshefte für Chemie - Chemical Monthly. 136:2035-2039
ISSN:	1434-4475 0026-9247
DOI:	10.1007/s00706-005-0364-1
Popis:	Primary phenylmethanols are selectively and efficiently oxidized to the corresponding aldehydes by the system C6H5IO/(C6H5)4PBr/CH2Cl2, T = 298 K under aerobic conditions. The use of the relatively stable iodosobenzene, an iodine(III) compound, in place of the usually employed and potentially explosive iodine(V) reagents, the easy work-up procedure, and the facile recycling of solvent and oxidant provides a convenient and environmentally benign oxidation method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::621870b0f73c231740aee0f8de791195 https://doi.org/10.1007/s00706-005-0364-1 Zobrazit plný text záznamu Full text from SpringerLink