Gel polymer electrolytes containing ionic liquids prepared by radical polymerization

Autor:	Li Libo, Yang Shuo, Li Jiesi, Guo Shaowen, Yang Pei-xia
Rok vydání:	2014
Předmět:	Materials science Inorganic chemistry Radical polymerization chemistry.chemical_element Electrolyte Conductivity Electrochemistry Dielectric spectroscopy chemistry.chemical_compound Colloid and Surface Chemistry chemistry Ionic liquid Lithium Thermal stability
Zdroj:	Colloids and Surfaces A: Physicochemical and Engineering Aspects. 459:136-141
ISSN:	0927-7757
DOI:	10.1016/j.colsurfa.2014.06.004
Popis:	s Gel polymer electrolytes containing N-propyl-methyl piperidinium bis(trifluoromethylsulfonyl)imide (PP13TFSI) ionic liquid were prepared by the radical polymerization method. Thermal and electrochemical properties had been determined for these gel polymer electrolytes. The gel electrolyte films with good thermal stability were flexible, smooth, self-standing and amorphous state. The increase of PP13TFSI content caused an increase of the conductivity, and the conductivity reached the value of 3.4 × 10−4 S cm−1 at higher PP13TFSI concentration (33.3 wt.%). The interfacial behavior of the Li|ILGPE|LiFePO4 battery cell was determined and analyzed by electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS). The results showed that the interface films between the electrode and the electrolyte had formed. The charge–discharge performance of the Li|ILGPE|LiFePO4 cell indicated the potential application of the as-prepared ILGPE-4 in lithium ion batteries.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::61ff837d09a65df4a4f4168fbf88c459 https://doi.org/10.1016/j.colsurfa.2014.06.004 Zobrazit plný text záznamu Full Text from ScienceDirect