Syntheses and photocatalytic performances of four coordination complexes constructed from 1,10-phenanthroline and polycarboxylic acids
| Autor: | Huan-Ping Jing, Xue-Yan Xu, Chong-Chen Wang, Xiao-Xu Song, Peng Wang, Shi-Jie Gao |
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| Rok vydání: | 2017 |
| Předmět: |
Chemistry
Phenanthroline Inorganic chemistry Metals and Alloys chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Copper Hydrothermal circulation 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound Materials Chemistry Photocatalysis Fourier transform infrared spectroscopy 0210 nano-technology Benzene Organometallic chemistry Nuclear chemistry |
| Zdroj: | Transition Metal Chemistry. 42:181-191 |
| ISSN: | 1572-901X 0340-4285 |
| DOI: | 10.1007/s11243-017-0123-2 |
| Popis: | Four coordination complexes of copper(II) and iron(II), namely [CuCl(phen)2](5-NO2-Hipa)·2H2O (BUC-10), [Cu(phen)(3,4-H2dczpb)(H2O)]·H2O (BUC-11), [Fe(phen)(L)(H2O)]2 (BUC-12), and [Fe(phen)3](3,4-H3dczpb)2·0.6H2O (BUC-13) (phen = 1,10-phenanthroline; 5-NO2-H2ipa = 5-nitroisophthalic acid; 3,4-H4dczpb = 3,4-dicarboxyl-(3′,4′-dicarboxylazophenyl) benzene; L = 6,12-dihydroxy-1,2,6,12-tetrahydroindazolo[2,1-a]indazole-1,7-dicarboxylic acid), have been synthesized under hydrothermal conditions. All four complexes were characterized by single-crystal X-ray diffraction, FTIR, elemental analysis and UV–Vis diffuse reflection spectroscopy. The photocatalytic performances of the complexes for decomposition of methylene blue under UV irradiation were also investigated. |
| Databáze: | OpenAIRE |
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