A Novel Bifunctional Ligand for the Synthesis of Polynuclear Alkynyl Complexes

Autor:	Maximilian Gaffga, Gereon Niedner-Schatteburg, Caroline Wilhelmi, Yu Sun, Werner R. Thiel
Rok vydání:	2014
Předmět:	chemistry.chemical_compound Chemistry Ligand Pyridine Organic chemistry chemistry.chemical_element General Chemistry Pyrazole Platinum Bifunctional Combinatorial chemistry Ruthenium
Zdroj:	Zeitschrift für Naturforschung B. 69:1290-1298
ISSN:	1865-7117 0932-0776
Popis:	The synthesis of 2-(1-(prop-2-yn-1-yl)-1H-pyrazol-3-yl)pyridine is presented. This ligand contains both, an alkynyl function being suitable for metal-carbon bond formation with electron-rich late transition metal sites, and a pyrazolylpyridine unit, which is well-known to undergo chelation reactions similar to 2,2′-bipyridine. This strategy allows building up polynuclear complexes with broad combinations of different metal sites. Two platinum alkynyl complexes were structurally characterized, and a trinuclear Ru2Pt complex was indentified by means of NMR spectroscopy and ESI mass spectrometry.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::61d8fb1072cbf9c875cfc96d6bb4a3bc https://doi.org/10.5560/znb.2014-4164 Zobrazit plný text záznamu