Synthesis of 2-trifluoromethoxyethyl trifluoromethoxyacetate and derived 2-trifluoromethoxyacrylates

Autor:	Angelika Wernicke, Elsa Anselmi, Jean-Claude Blazejewski, Claude Wakselman
Rok vydání:	2002
Předmět:	Organic Chemistry Condensation Deamination Ether medicine.disease Biochemistry Inorganic Chemistry chemistry.chemical_compound chemistry medicine Environmental Chemistry Organic chemistry Dehydration Physical and Theoretical Chemistry
Zdroj:	Journal of Fluorine Chemistry. 117:161-166
ISSN:	0022-1139
Popis:	The synthesis of 2-trifluoromethoxyethyl trifluoromethoxyacetate 2 by oxidation of bis(2-trifluoromethoxyethyl)ether 1 followed by its anionic condensation with aldehydes, ketones and immonium salts under mild conditions, and further dehydration or deamination, enabled the preparation of 3-aryl and 3-alkyl-2-trifluoromethoxacrylates 8a–e as well as the parent 2-trifluoromethoxyacrylate 8f.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::61cdf376aef57a757212fe862a198e37 https://doi.org/10.1016/s0022-1139(02)00152-5 Zobrazit plný text záznamu Full Text from ScienceDirect