Ionothermal synthesis, characterization of a new layered gallium phosphate with an unusual heptamer SBU
| Autor: | Liangliang Huang, Yike Ma, Shufei Jiao, Yanfeng Bi, Yansong Jiang, Fan Gao |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Denticity 010405 organic chemistry Inorganic chemistry chemistry.chemical_element Ethylenediamine Crystal structure 010402 general chemistry Condensed Matter Physics 01 natural sciences Gallium phosphate 0104 chemical sciences Electronic Optical and Magnetic Materials Deep eutectic solvent Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Materials Chemistry Ceramics and Composites SBus Physical and Theoretical Chemistry Gallium Choline chloride |
| Zdroj: | Journal of Solid State Chemistry. 254:155-159 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2017.07.010 |
| Popis: | A new layered gallium phosphate Ga 3 (PO 4 ) 4 (C 2 N 2 H 8 )·(H 2 C 2 N 2 H 8 ) 2 ·Cl (compound 1 ), has been ionothermally synthesized in the presence of deep eutectic solvent (DES) comprising mixtures of choline chloride and 2-imidazolidone (IMI). Single-crystal X-ray diffraction analysis reveals that compound 1 shows 2D layered framework with 10-ring windows, which is constructed from unusual heptamer second building units (SBUs). The ethylenediamine (en) units deriving from the decomposition of IMI, play a dual role as bidentate ligands coordinated with 6-fold coordinate gallium atoms and the templates. Additionally, compound 1 shows photoluminescence property in solid state at room temperature. |
| Databáze: | OpenAIRE |
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