Some coordination compounds of phenylzirconium trichloride
| Autor: | David A. Rice, G. W. A. Fowles, John F. Clarke |
|---|---|
| Rok vydání: | 1974 |
| Předmět: |
chemistry.chemical_classification
Denticity Cyanide Organic Chemistry Infrared spectroscopy Biochemistry Medicinal chemistry Coordination complex Adduct Inorganic Chemistry chemistry.chemical_compound chemistry Pyridine Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Triphenylphosphine Tetrahydrofuran |
| Zdroj: | Journal of Organometallic Chemistry. 76:349-353 |
| ISSN: | 0022-328X |
| Popis: | Phenylzirconium trichloride has been isolated as its tetrahydrofuran adduct PhZrCl 3 ·3thf (I). The reaction of I with a range of nitrogen, phophorus and sulphur ligands gave products of stoichiometry PhZrCl 3 ·thf·L (L = 2,2′-bipyridyl, 4,4′-bipyridyl, 2-methylpyridine or triphenylphosphine) and PhZrCl 3 ·thf·2L′ (L′ = pyridine, PhCN or 1,4-thioxan). Reaction of I with methyl cyanide gave PhZrCl 3 ·2CH 3 CN, which reacted with bidentate donors to give complexes of formula PhZrCl 3 ·L (L = 2,2′-bipy, 4,4′-bipy or Ph 2 PCH 2 CH 2 PPh 2 ). The adducts were characterised by analysis, NMR and infrared spectroscopy. |
| Databáze: | OpenAIRE |
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