Clean preparation of S-thiocarbamates with in situ generated hydroxide in 2-methyltetrahydrofuran
| Autor: | Ying-Wu Lin, Jia-Xi Tan, Wen-Hu Bao, Zheng Wang, Qin Zhu, Zhong Cao, Wei-Min He, Xiao Tang, Yun-Fu Zhang |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Hydrogen Chemistry 2-Methyltetrahydrofuran Aryl Inorganic chemistry chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Nitrogen Oxygen 0104 chemical sciences chemistry.chemical_compound Hydroxide 0210 nano-technology Thiocarbamates Alkyl |
| Zdroj: | Chinese Chemical Letters. 30:2259-2262 |
| ISSN: | 1001-8417 |
| DOI: | 10.1016/j.cclet.2019.06.052 |
| Popis: | A simple and clean protocol for the synthesis of various alkyl and (hetero)aryl S-thiocarbamates was established. The usage of in situ generated hydroxide as both an oxygen source and hydrogen source as well as biomass-derived 2-methyltetrahydrofuran as a green reaction medium, the avoidance of phosphorus-containing reductant, and the generation of harmless water and nitrogen as the side-products have given the present method atom-economy and environmental friendliness. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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