Role of structural elements of chloronaphthalene molecules in spin-orbit coupling: Phosphorescence
| Autor: | E. A. Gastilovich, V. G. Klimenko, N. V. Korol’kova, R. N. Nurmukhametov |
|---|---|
| Rok vydání: | 2010 |
| Předmět: |
chemistry.chemical_element
Spin–orbit interaction Atomic and Molecular Physics and Optics Electronic Optical and Magnetic Materials Coupling (electronics) Compensation effect Crystallography chemistry.chemical_compound Dipole Nuclear magnetic resonance chemistry Molecule Physics::Chemical Physics Phosphorescence Carbon Naphthalene |
| Zdroj: | Optics and Spectroscopy. 108:486-494 |
| ISSN: | 1562-6911 0030-400X |
| DOI: | 10.1134/s0030400x10030264 |
| Popis: | The dipole moments (P s ) of the T 1 → S 0 transition from the triplet sublevels s = z, y, x, which are determined by the spin-orbit (SO) coupling, are studied for a series of mono- and dichloro derivatives of naphthalene. Based on the model calculations, the effects of different factors (SO coupling in individual chlorine atoms occupying the α and β positions in the molecule, SO coupling in the carbon backbone of the molecule, and the compensation effect caused by the interference of SO interactions in individual structural elements of the molecule) on P s are differentiated and discussed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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