Preparation and Properties of Glucose Derivatives having Polymerizable Group: I-Characterization of Glucose Derivatives Prepared with Methacryl Isocyanate Compound

Autor:	Toshihisa Miura, Eiji Nakanishi, Aiko Ogawa, Katsuhiro Inomata, Shinji Hirata, Hideki Sugimoto
Rok vydání:	2006
Předmět:	chemistry.chemical_compound Mechanical property Ethyl isocyanate chemistry Polymerization Molar ratio Isocyanate compound Polymer chemistry Organic chemistry Ethyl carbamate Thermal stability General Medicine Fiber
Zdroj:	Sen'i Gakkaishi. 62:130-134
ISSN:	1884-2259 0037-9875
Popis:	In this study, glucose derivatives as novel binders for fiber board, 2-(methacryloyloxy)ethyl carbamate glucose (MOCG), was prepared by reaction of 2-(methacryloyloxy)ethyl isocyanate (MOI) and OH group of glucose. MOCGs which controlled the substitution degree were also prepared by changing the molar ratio of glucose and MOI. The MOCGs were polymerized and physical properties of MOCG homopolymers were evaluated. High substituted MOCG homopolyer showed excellent mechanical property and thermal stability. On the other hand, physical properties of low substituted MOCG homopolymer was lowered by the aggregation of the glucose unit.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6178117a8fc1a710b965c43cdd51b721 https://doi.org/10.2115/fiber.62.130 Zobrazit plný text záznamu