Second-order non-linear optical properties of diironalkenylidyne complexes; crystal structure of {(η-C5H5)2Fe2(CO)2(μ-CO)(μ-(E)CCHCHC6H4(p)-NMe2)}+BF4−

Autor:	David Bloor, Mark E. Thompson, P. V. Kolinsky, Heather E. Bunting, Judith A. Bandy, Malcolm L. H. Green, Joseph W. Perry, Seth R. Marder, R. J. Jones, Maria-Helena Garcia
Rok vydání:	1992
Předmět:	Tertiary amine Stereochemistry Order (ring theory) Second-harmonic generation Crystal structure Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry X-ray crystallography Materials Chemistry Urea Molecule Physical and Theoretical Chemistry Carbene
Zdroj:	Polyhedron. 11:1429-1435
ISSN:	0277-5387
Popis:	The second-order non-linear optical properties of a series of diironalkenylidyne complexes have been examined by the Kurtz powder technique. One compound, {(η-C5H5)2Fe2(CO)2(μ-CO)(μ-(E)CCHCHC6H4(p)-N(CH3)2)}+CF3SO3−, exhibited a powder efficiency for second harmonic generation 3.6 times that of a urea reference standard (ω = 1907 nm, 2ω = 953.5 nm). The crystal structure of {(η-C5H5)2Fe2(CO)2(μ-CO)(μ-(E)CCHCHC6H4(p)-N(CH3)2)}+BF4− has been determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::61381a4c6914811d3013205ffa2b20d7 https://doi.org/10.1016/s0277-5387(00)83135-6 Zobrazit plný text záznamu