A Preliminary Study of the Carboxylation and Decarboxylation of Some Sulfides

Autor: Yong He Kim, Kenji Ueyama, Yoshinori Ikeda, Isao Minamida, Waichiro Tagaki, Shigeru Oae
Rok vydání: 1966
Předmět:
Zdroj: Bulletin of the Chemical Society of Japan. 39:917-920
ISSN: 1348-0634
0009-2673
DOI: 10.1246/bcsj.39.917
Popis: Some sulfides with benzylic hydrogen have been carboxylated by carbonating the respective carbanions generated with dimsylsodium in dimethyl sulfoxide. The resulting mercaptocarboxylic acids have then been found to have considerably-enhanced rates of decarboxylation reaction.
Databáze: OpenAIRE