Study on the role of Pt and Pd in Pt–Pd/TiO2 bimetallic catalyst for H2 oxidation at room temperature
| Autor: | Jung Hun Shin, Geo Jong Kim, Sung Chang Hong |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Materials science
Hydrogen Renewable Energy Sustainability and the Environment Inorganic chemistry Energy Engineering and Power Technology chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Redox 0104 chemical sciences Catalysis Metal Fuel Technology Hydrogen safety X-ray photoelectron spectroscopy chemistry visual_art visual_art.visual_art_medium Hydrogen fuel enhancement 0210 nano-technology Bimetallic strip |
| Zdroj: | International Journal of Hydrogen Energy. 45:17276-17286 |
| ISSN: | 0360-3199 |
| DOI: | 10.1016/j.ijhydene.2020.03.062 |
| Popis: | The hydrogen safety issue is spotlighted as the hydrogen process is extended. For this reason, we studied catalysts for H2 oxidation at room temperature to ensure hydrogen safety. Catalysts were prepared by different preparation methods and compared to evaluate the role of Pt and Pd in Pt–Pd/TiO2 catalysts. The catalytic activity was significantly enhanced when activity metal size was small and it was exposed to catalyst surface to a high Pd ratio. For the 0.1%Pt-0.9%Pd/TiO2 catalyst, high hydrogen conversion of 90% was obtained under the condition of 0.5% hydrogen injection. To understand the correlation between activity and characteristics of catalyst, the physicochemical characteristics of the various catalysts were investigated by X-ray photoelectron spectroscopy (XPS), temperature-programmed oxidation and reduction (TPOR) and Field Emission-Transmission Electron Microscope (FE-TEM) analysis. From these analysis, it was found that Pt served the role of highly dispersion of active metal (Pt–Pd) and as with increasing Pd ratio of active metal, hydrogen activity was increased, which indicates that hydrogen oxidation had proceeded on the Pd site. Finally, the valence state of the Pd influenced hydrogen oxidation activity of Pt–Pd/TiO2, which increased with increasing ratio of Pd0/PdTotal. |
| Databáze: | OpenAIRE |
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