| Autor: |
Feng Yuan, Ai Hong Guo, Chun Na Zhang, Wen Bo Su |
| Rok vydání: |
2013 |
| Předmět: |
|
| Zdroj: |
Advanced Materials Research. 700:11-14 |
| ISSN: |
1662-8985 |
| DOI: |
10.4028/www.scientific.net/amr.700.11 |
| Popis: |
Lithium-ion secondary cell has high energy density, stable and high working voltage, wide working temperature and long working term. It is a safe and clean energy resource without pollution. At present, Lithium Hexafluorophosphate is used as conducting electrolyte lithium salt in lithium-ion secondary batteries. But Lithium Hexafluorophosphate as conducting electrolyte lithium salt has some disadvantages such as hydrolysis and instability. Lithium Bis (heptafluoroisopropyl) t-etrafluorophosphate Li [(C3F7)2PF4] was received by simons process from diisopropylchlorophosphane in this paper. As electrolyte of Li ion secondary cell, Li [(C3F7)2PF4] had lower vapor pressure than LiPF6 in the solvent in the same temperature, comparable conductivity and oxidation stability in the same concentration in room temperature. It was worth mentioning that Li [(C3F7)2PF4] has excellent stability towards hydrolysis. The synthesis process is safe and easily controlled. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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