Concerning the ability of oligooxyquinoline to accumulate reversibly bound oxygen

Autor:	B.A. Mamedov, Sh.I. Mustafaeva, A.V. Ragimov
Rok vydání:	1990
Předmět:	Polymers and Plastics Organic Chemistry Inorganic chemistry Oxide chemistry.chemical_element Activation energy Oligomer Oxygen Decomposition Gel permeation chromatography chemistry.chemical_compound Reaction rate constant chemistry Materials Chemistry Organic chemistry Chemical decomposition
Zdroj:	Polymer. 31:1968-1970
ISSN:	0032-3861
DOI:	10.1016/0032-3861(90)90025-t
Popis:	A study was performed to find and then to optimize the conditions under which alkaline solutions of H2O2 convert 8-oxyquinoline into an oligomeric oxide. According to infra-red and ultra-violet spectroscopy and gel permeation chromatography data, the oligomer consists mostly of oxyquinolineN-oxide repeat units. A kinetic study of the decomposition of this oligomeric oxide under the action of sulphuric acid in the temperature range 313–343 K showed that up to 6.8 litres of free oxygen were liberated per 100 g of the oligomer. The first-order rate constant at 333 K and activation energy for decomposition were6.05 × 10−4s−1 and 99.2 kJ mol−1 respectively.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6103bfa7ff2ba2bcb3511e7bfafb5e4c https://doi.org/10.1016/0032-3861(90)90025-t Zobrazit plný text záznamu