Gram-Scale Preparation of Pd@PANI: A Practical Catalyst Reagent for Copper-Free and Ligand-Free Sonogashira Couplings
| Autor: | Zhe Han, Yuanhua Ding, Lei Yu |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Chemistry
Organic Chemistry Inorganic chemistry chemistry.chemical_element Sonogashira coupling 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Combinatorial chemistry Copper 0104 chemical sciences Catalysis chemistry.chemical_compound Aniline Polymerization Reagent Polyaniline Physical and Theoretical Chemistry 0210 nano-technology Palladium |
| Zdroj: | Organic Process Research & Development. 20:2124-2129 |
| ISSN: | 1520-586X 1083-6160 |
| DOI: | 10.1021/acs.oprd.6b00322 |
| Popis: | Palladium nanoparticles on the polyaniline (Pd@PANI) catalyst are now easily prepared on a gram scale through the oxidative polymerization of aniline in the presence of PdCl2 by using air as a clean oxidant. The material is found to be very stable and can be stored for more than one year without deactivation. Thus, it may become a commercial reagent in organic synthesis, depending on its application scopes. This article reported the first example of Pd@PANI-catalyzed Sonogashira couplings free of copper and ligands. |
| Databáze: | OpenAIRE |
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