Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(ii) and palladium(ii) azuliporphyrinsPart 20 of the series ‘Conjugated Macrocycles Related to the Porphyrins’. Part 19: S. R. Graham, D. A. Colby and T. D. Lash, Angew. Chem., 2002, in press
| Autor: | Timothy D. Lash, Gregory M. Ferrence, Shelley R. Graham |
|---|---|
| Rok vydání: | 2002 |
| Předmět: |
inorganic chemicals
Chemistry Metals and Alloys chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy humanities Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Characterization (materials science) Nickel chemistry.chemical_compound Materials Chemistry Ceramics and Composites Organic chemistry Chelation Brief treatment Organometallic chemistry Palladium Group 2 organometallic chemistry |
| Zdroj: | Chemical Communications. :894-895 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Brief treatment of azuliporphyrins 5 with nickel(II) or palladium(II) acetate in refluxing DMF afforded excellent yields of the related chelates; these novel organometallic compounds retain cross-conjugated borderline aromatic structures as judged by UV-Vis and NMR spectroscopy, and X-ray crystallography. |
| Databáze: | OpenAIRE |
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