Raman scattering in sputtered amorphous Ge25Se75-xBix films

Autor: D. Papadimitriou, B. S. Chao, E. Mytilineou
Rok vydání: 1996
Předmět:
Zdroj: Journal of Non-Crystalline Solids. 195:279-285
ISSN: 0022-3093
DOI: 10.1016/0022-3093(95)00571-4
Popis: Raman spectra of sputtered amorphous Ge25Se75-xBix films, with x from 0 to 19, have been studied. For x = 0 the typical spectrum of an amorphous GeSe3 glass is obtained. It is dominated by the peaks at 200 and 220 cm−1, characteristic of the Ge(Se 1 2 ) 4 tetrahedra and a broad peak at 265 cm−1, due to the excess SeSe bonds. The intensity of the 200, 220, 265 cm−1 peaks decrease and a new broad asymmetric peak appears at 175 cm−1 whose intensity increases with the increase of the amount of Bi incorporated into the films. This later peak is attributed to Bi2Se3 structural units.
Databáze: OpenAIRE