A Comparison of Metal-Loaded DOW3N Ion Exchangers for Removal of Perchlorate from Water

Autor: Steven E. Mylon, Dongye Zhao, Arthur D. Kney, Paul S. Dimick, Javad Tavakoli
Rok vydání: 2008
Předmět:
Zdroj: Separation Science and Technology. 43:2343-2362
ISSN: 1520-5754
0149-6395
DOI: 10.1080/01496390802118921
Popis: In this work, an alternative class of perchlorate selective ion exchangers (known as polymeric ligand exchangers, PLEs) were prepared by loading six transition metals (Cu(II), Co(II), Zn(II), Ni(II), Fe(II), and Fe(III)) onto a commercially available chelating resin Dowex M4195 (DOW3N). The resultant PLEs (DOW3N-Me, where Me = one of the metals) were tested with respect to their perchlorate selectivity, capacity, kinetics, and regeneration efficiency through a series of batch and column experiments. Within this group of PLEs, DOW3N-Cu(II) showed the highest perchlorate capacity; all four PLEs had similar perchlorate sorption kinetics; and DOW3N-Fe(III) demonstrated better regeneration potential.
Databáze: OpenAIRE