Phosphorylation of Benzimidazole-2-thiones by Chloroethynylphosphonate

Autor:	Yu. L. Piterskaya, D. D. Kartsev, D. M. Egorov, M. N. Krivchun, V. A. Polukeev, Albina V. Dogadina
Rok vydání:	2018
Předmět:	chemistry.chemical_classification Benzimidazole chemistry.chemical_compound 010405 organic chemistry Chemistry Regioselectivity Phosphorylation General Chemistry 010402 general chemistry 01 natural sciences Medicinal chemistry Alkyl 0104 chemical sciences
Zdroj:	Russian Journal of General Chemistry. 88:1824-1831
ISSN:	1608-3350 1070-3632
DOI:	10.1134/s1070363218090104
Popis:	The reaction of chloroethynylphosphonates with N-substituted benzimidazole-2-thiones proceeded chemo- and regioselectively with the formation of cyclic zwitterions, namely alkyl (9H-benzo[4,5]imidazo[2,1-b]-thiazol-3-yl-4-ium)phosphonates. Chemo- and regioselective reaction of N-unsubstituted benzimidazole-2-thione with chloroethynylphosphonates led to the production of linear Z-1,2-bis(1H-benzimidazol-2-ylsulfanyl)-ethenylphosphonates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::60e987818f0251fe1862c346d900857b https://doi.org/10.1134/s1070363218090104 Zobrazit plný text záznamu Plný text ve formátu PDF