A model of gas transfer across air-water interfaces with capillary waves

Autor: Michel Coantic
Rok vydání: 1986
Předmět:
Zdroj: Journal of Geophysical Research. 91:3925
ISSN: 0148-0227
DOI: 10.1029/jc091ic03p03925
Popis: The transfer of weakly soluble gases between the atmosphere and seas or lakes is controlled by liquid-phase molecular and turbulent diffusion mechanisms, which essentially depend on wind velocity and gas Schmidt number. A distinct change in regime is observed around 2–3 m s−1, when capillary waves appear, which present models cannot explain. We suggest relating turbulent diffusivity with (1) possible motions close to a “free” liquid-gas interface, (2) mean current distribution in that region, and (3) capillary wave spectra. Resulting transfer velocities explain laboratory and field data at low and moderate wind speeds.
Databáze: OpenAIRE