Synthesis and crystal structure of two novel polymeric PbII compounds: [Pb(phen)(N3)2]n and [Pb(deta)(N3)·(N3)]n

Autor:	Hoong-Kun Fun, Farzin Marandi, AA Soudi, Babak Mirtamizdoust
Rok vydání:	2007
Předmět:	Inorganic Chemistry chemistry.chemical_classification chemistry.chemical_compound Crystallography Chemistry Coordination polymer Inorganic chemistry Materials Chemistry Stacking Azide Polymer Crystal structure Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry Communications. 10:174-177
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2006.10.017
Popis:	Two novel 1D polymeric Pb(II) complex containing the Pb 2 -(μ-N 3 ) 2 units, [Pb(phen)(N 3 ) 2 ] n ( 1 ) and [Pb(deta)(N 3 ) · (N 3 )] n (2) (deta and phen are the abbreviations of diethylentriamine and 1,10-phenanthroline, respectively) have been synthesized and characterized by single-crystal X-ray diffraction. Compounds of ( 1 ) and ( 2 ) are six, PbN 6 , and five, PbN 5 , coordinated polymers, respectively. Both of them hold hemidirected coordination geometries. To the best of our knowledge, these 1D coordination polymers are the novel Pb 2 -(μ-N 3 ) 2 units of lead(II) compounds and interact with each other via π–π stacking and weak Pb⋯N interactions to create 3D and 2D frameworks.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::60af6fefd5d58968b184e7379d08b250 https://doi.org/10.1016/j.inoche.2006.10.017 Zobrazit plný text záznamu Full Text from ScienceDirect