Regioselective Acylation of 3,4-OH Free d-Glucosamines: A Rapid Access to Orthogonally Functionalized Building Blocks

Autor:	Mickael Virlouvet, Markus Sebastian Ehret, Moritz Bosse Biskup
Rok vydání:	2010
Předmět:	Acylation chemistry.chemical_compound chemistry Glucosamine Acetylation Stereochemistry Organic Chemistry Acetal Organic chemistry Regioselectivity Protecting group Catalysis
Zdroj:	Synthesis. 2010:3481-3485
ISSN:	1437-210X 0039-7881
DOI:	10.1055/s-0030-1258200
Popis:	A method for the regioselective O-acylation of 3,4-OH free D-glucosamines via stannylene acetal methodology was developed. From fully acetylated 2-N-trichloroacetyl-D-glucosamine, 4-OH free D -glucosamine derivatives bearing orthogonal protecting group patterns were prepared.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::60938263b32a548b59cf67eace30c1e8 https://doi.org/10.1055/s-0030-1258200 Zobrazit plný text záznamu