The Reaction of (1,3,4-Oxadiazole-Thiolato) Mercury(II) with Triphenyl Phosphine
Autor: | Eric C. Hosten, Hikmat Ali Mohamad, Thomas Gerber |
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Rok vydání: | 2020 |
Předmět: |
010302 applied physics
Ethanol Chemistry Infrared Oxadiazole chemistry.chemical_element General Chemistry Nuclear magnetic resonance spectroscopy 010403 inorganic & nuclear chemistry Condensed Matter Physics 01 natural sciences 0104 chemical sciences Mercury (element) chemistry.chemical_compound 0103 physical sciences General Materials Science Triphenylphosphine Phosphine Nuclear chemistry |
Zdroj: | Crystallography Reports. 65:1117-1120 |
ISSN: | 1562-689X 1063-7745 |
Popis: | The reaction of 5-phenyl-1,3,4-oxadiazole-2-thiol with mercury(II) acetate in ethanol led to the isolation of the complex [Hg(L)2] (1). Further reaction of 1 with a twofold molar excess of triphenylphosphine led to the isolation of [Hg(L)2(PPh3)2] (2). The complex 2 was characterized by infrared, ultraviolet–visible and nuclear magnetic resonance spectroscopy techniques, as well as by X-ray diffraction analysis. |
Databáze: | OpenAIRE |
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