Hydrohalogenation of N-acetyl(aroyl)-1,4-benzoquinone monoimines
Autor: | Svetlana A. Konovalova, A. P. Avdeenko, O. N. Ludchenko, O. P. Ledeneva, A. V. Vakulenko |
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Rok vydání: | 2011 |
Předmět: | |
Zdroj: | Russian Journal of Organic Chemistry. 47:214-229 |
ISSN: | 1608-3393 1070-4280 |
DOI: | 10.1134/s1070428011020102 |
Popis: | New N-acetyl-1,4-benzoquinone monoimines alkyl-substituted in the quinoid ring were synthesized. The hydrohalogenation of N-acetyl(aroyl)-1,4-benzoquinone monoimines proceeds exclusively in keeping with the 1,4-addition. The hydrochlorination occurs along the ionic mechanism, in the hydrobromination grows the role of the radical mechanism. |
Databáze: | OpenAIRE |
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