Hydrohalogenation of N-acetyl(aroyl)-1,4-benzoquinone monoimines

Autor: Svetlana A. Konovalova, A. P. Avdeenko, O. N. Ludchenko, O. P. Ledeneva, A. V. Vakulenko
Rok vydání: 2011
Předmět:
Zdroj: Russian Journal of Organic Chemistry. 47:214-229
ISSN: 1608-3393
1070-4280
DOI: 10.1134/s1070428011020102
Popis: New N-acetyl-1,4-benzoquinone monoimines alkyl-substituted in the quinoid ring were synthesized. The hydrohalogenation of N-acetyl(aroyl)-1,4-benzoquinone monoimines proceeds exclusively in keeping with the 1,4-addition. The hydrochlorination occurs along the ionic mechanism, in the hydrobromination grows the role of the radical mechanism.
Databáze: OpenAIRE