Caesium tetrathiotungstate(VI). Matrix isolation and mass spectrometric studies of a ternary sulphide which is stable in the vapour

Autor:	Nigel A. Young, Peter J. Jones, Ian R. Beattie, Andrew D. Willson
Rok vydání:	1988
Předmět:	Neon Argon chemistry Caesium Matrix isolation Analytical chemistry chemistry.chemical_element General Chemistry Mass spectrometry Ternary operation Nitrogen Ion Nuclear chemistry
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :2047
ISSN:	1364-5447 0300-9246
DOI:	10.1039/dt9880002047
Popis:	Cs2WS4 can be sublimed at approximately 800 °C in vacuo(ca. 10–5 Torr). The major species detected mass spectrometrically is the parent ion. Matrix-isolation i.r. studies suggest but do not prove that the molecule has a structure similar to that adopted by M2XO4 species (where M is an alkali-metal ion and X = S, Cr, Mo, or W). In argon and nitrogen matrices the symmetry appears to be lower than that in neon.
Databáze:	OpenAIRE
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