Metal–Metal and Metal–Ligand Bonding in Trinuclear Vinylidene Rhenium-Iron-Platinum Complex Studied by Topological Analysis of Electron Density

Autor:	Aleksey M. Shor, Anatoly I. Rubaylo, Svetlana S. Laletina, Elena A. Ivanova-Shor
Rok vydání:	2020
Předmět:	Electron density Materials science Iron platinum Ligand General Chemical Engineering chemistry.chemical_element General Chemistry Rhenium Metal Crystallography chemistry visual_art visual_art.visual_art_medium Metal metal
Zdroj:	Journal of Siberian Federal University. Chemistry. :553-564
ISSN:	2313-6049 1998-2836
DOI:	10.17516/1998-2836-0205
Popis:	Metal–metal and metal–ligand bonding in vinylidene ReFePt complex was studied by density functional method and topological analysis of electron density. Topological analysis did not found direct bonding between the metal atoms pointing to indirect metal–metal interaction mediated via the bridging vinylidene ligand. At the same time, the delocalization index δ(Fe,Pt) reveals the strong Fe–Pt interaction that allows for supposing a chemical bonding between these atoms
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::606be841b8a3932362feb4ec7b544eb6 https://doi.org/10.17516/1998-2836-0205 Zobrazit plný text záznamu