Anode volt-amperometry of aminopyridines and aminopicolines

Autor: L. V. Chervina, I. B. Romanova
Rok vydání: 1977
Předmět:
Zdroj: Chemistry of Heterocyclic Compounds. 13:1321-1324
ISSN: 1573-8353
0009-3122
Popis: The electrochemical behavior of amino derivatives of pyridine — 2-, 3-, and 4-aminopyridines, 2-amino-3-methylpyridine, 2-amino-4-methylpyridine, 4-amino-3-methylpyridine, and 2,6-diaminopyridine — during their oxidation on a rotating platinum microanode in acetonitrile and aqueous alcohol was investigated. Differences associated with the electronic effect of the substituent were uncovered during the electrical oxidation of the indicated compounds. The data obtained make it possible to conclude that the magnitude of the current strength in the oxidation of aminopyridines is determined by the rate of diffusion of the depolarizer to the electrode.
Databáze: OpenAIRE