Anode volt-amperometry of aminopyridines and aminopicolines
Autor: | L. V. Chervina, I. B. Romanova |
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Rok vydání: | 1977 |
Předmět: | |
Zdroj: | Chemistry of Heterocyclic Compounds. 13:1321-1324 |
ISSN: | 1573-8353 0009-3122 |
Popis: | The electrochemical behavior of amino derivatives of pyridine — 2-, 3-, and 4-aminopyridines, 2-amino-3-methylpyridine, 2-amino-4-methylpyridine, 4-amino-3-methylpyridine, and 2,6-diaminopyridine — during their oxidation on a rotating platinum microanode in acetonitrile and aqueous alcohol was investigated. Differences associated with the electronic effect of the substituent were uncovered during the electrical oxidation of the indicated compounds. The data obtained make it possible to conclude that the magnitude of the current strength in the oxidation of aminopyridines is determined by the rate of diffusion of the depolarizer to the electrode. |
Databáze: | OpenAIRE |
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