Electrochemical CO2 reduction catalyzed by atomically precise alkynyl-protected Au7Ag8, Ag9Cu6, and Au2Ag8Cu5 nanoclusters: probing the effect of multi-metal core on selectivity
| Autor: | Xiaoshuang Ma, Fang Sun, Lubing Qin, Yonggang Liu, Xiongwu Kang, Likai Wang, De-en Jiang, Qing Tang, Zhenghua Tang |
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| Rok vydání: | 2022 |
| Předmět: | |
| Zdroj: | Chemical Science. 13:10149-10158 |
| ISSN: | 2041-6539 2041-6520 |
| DOI: | 10.1039/d2sc02886g |
| Popis: | We report the first all-alkynyl-protected Au2Ag8Cu5 cluster, which adopts a M@M8@M6 core configuration similar with Au7Ag8/Ag9Cu6 clusters. The three clusters exhibited strong metal core effect toward CO2RR, which was understood by DFT calculations. |
| Databáze: | OpenAIRE |
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