Polar and anchimeric effects in the solvolysis of 6-endo-substituted 2-norbornyl-p-toluene-sulfonates

Autor:	Cyril A. Grob, Bettina Günther, Reinhard Hanreich
Rok vydání:	1981
Předmět:	Steric effects chemistry.chemical_compound Chemistry Organic Chemistry Drug Discovery Polar Organic chemistry Reactivity (chemistry) Solvolysis Biochemistry Medicinal chemistry 2-Norbornyl cation Toluene
Zdroj:	Tetrahedron Letters. 22:1211-1214
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(01)90276-x
Popis:	A study of the influence of 6-endo substituents on the reactivity of 2-exo- and 2-endo-norbornyl p-toluenesulfonates 3 and 4 , respectively, confirms that polar rather than steric effects control relative rates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::6036ca4b25196580337764a89b8eee82 https://doi.org/10.1016/s0040-4039(01)90276-x Zobrazit plný text záznamu