N-heterocyclic carbenes: novel ruthenium–alkylidene complexes
| Autor: | Florian J. Kohl, Thomas Weskamp, Wolfgang A. Herrmann |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
Olefin metathesis
Transition metal carbene complex Organic Chemistry chemistry.chemical_element Homogeneous catalysis Biochemistry Catalysis Ruthenium Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Materials Chemistry Ring-opening metathesis polymerisation Organic chemistry Physical and Theoretical Chemistry Carbene Acyclic diene metathesis |
| Zdroj: | Journal of Organometallic Chemistry. 582:362-365 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(99)00163-1 |
| Popis: | Ruthenium-based catalysts for olefin metathesis have attained enormous attention during the past years. Recently we have shown that the application of N -heterocyclic carbenes extends and complements the ubiquitous phosphanes. We now report on new members of our family of ruthenium-based catalysts for olefin metathesis. The synthesis of novel mixed carbene/phosphane- and homo- and heterobimetallic rutheniumalkylidene complexes is presented. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect