A new diene, 2-methoxy-1,3-pentadiene-5-ol. Synthesis and intramolecular diels-alder reactions

Autor:	Jan Becher, Mikael Begtrup, Tine Jørgensen, Helle Chris Nielsen, Nageshwar Malhotra
Rok vydání:	1992
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Fumaric acid chemistry Bicyclic molecule Intramolecular reaction Diene Intramolecular force Organic Chemistry Diol Organic chemistry Maleic anhydride Lactone
Zdroj:	Journal of Heterocyclic Chemistry. 29:1841-1845
ISSN:	1943-5193 0022-152X
DOI:	10.1002/jhet.5570290727
Popis:	Reactions of the diene 1-benzyloxy-2-methoxy-1,3-pentadiene-5-ol in intramolecular Diels-Alder reactions using maleic anhydride or fumaric acid ethyl ester is described. The new reactive diene is prepared starting from 3-methoxypyridine. The structure of the diene was elucidated by a NOE nmr experiment.
Databáze:	OpenAIRE
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